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Journal Articles

Control of biodegradability of poly(3-hydroxybutyric acid) film with grafting acrylic acid and thermal remolding

Wada, Yuki; Mitomo, Hiroshi*; Kasuya, Kenichi*; Nagasawa, Naotsugu; Seko, Noriaki; Katakai, Akio; Tamada, Masao

Journal of Applied Polymer Science, 101(6), p.3856 - 3861, 2006/09

 Times Cited Count:21 Percentile:53.63(Polymer Science)

Radiation-induced graft polymerization of acrylic acid (AAc) on the surface of poly(3-hydroxybutyric acid) (PHB) film was carried out by applying pre-irradiation techniques. The PHB films grafted with AAc (PHB-g-AAc) possessed a degree of grafting higher than 5% have completely lost the enzymatic degradability. The enzymatic degradability of the grafted film was recovered by remolding. And the highest enzymatic degradation rate was observed to grafted films with AAc 10% of degree. Difference of enzymatic degradability of PHB-g-AAc film was caused by decrement of amount of enzyme contact and decrement of crystallinity of PHB by remolding.

Journal Articles

Preparation of crosslinked fluoropolymer electrolyte membranes for use in fuel cells and then investigated their structural properties

Inoue, Yutaka; Kobayashi, Kazuhiro; Yamaki, Tetsuya; Asano, Masaharu; Kubota, Hitoshi*; Yoshida, Masaru

Dai-2-Kai 21-Seiki Rengo Shimpojiumu; Kagaku Gijutsu To Ningen Rombunshu, p.257 - 260, 2003/00

We prepared crosslinked fluoropolymer electrolyte membranes for use in fuel cells and then investigated their structural properties by X-ray diffraction (XRD) analysis. The radiation-induced grafting of styrene into crosslinked polytetrafluoroethylene (PTFE) films and subsequent sulfonation enabled us to obtain the electrolyte membrane with a sufficient ion exchange capacity, which exceeds that of the commercially-available film, Nafion. As the crosslinking and styrene grafting reactions proceeded, the size of the PTFE crystallites in the film became smaller, thereby decreasing the film crystallinity. Interestingly, in contrast to Nafion, the resulting sulfonated membranes were found to have high crystallinity.

Journal Articles

Irradiation effects of polyethylene produced by single-site catalyst

*; *; *; Yagi, Toshiaki; Morita, Yosuke

Denki Gakkai; Yuden, Zetsuen Zairyo Kenkyukai Shiryo DEI-97-147$$sim$$155, p.13 - 18, 1997/12

no abstracts in English

Journal Articles

Effect of irradiation on the degradability of polypropylene in the natural environment

Yoshii, Fumio; G.Meligi*; Sasaki, T.; Makuuchi, Keizo; A.M.Rabie*; *

Polym. Degrad. Stab., 49, p.315 - 321, 1995/00

 Times Cited Count:36 Percentile:82.08(Polymer Science)

no abstracts in English

Journal Articles

Structural changes of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) fractionated with acetone-water solution

Mitomo, Hiroshi*; Morishita, Norio; *

Polymer, 36(13), p.2573 - 2578, 1995/00

 Times Cited Count:49 Percentile:87.45(Polymer Science)

no abstracts in English

Journal Articles

Radiation grafting of hydrophilic monomers onto poly(4-methylpentene-1), I; Grafting of acrylic acid

Y.S.Soebianto*; ; ;

Angewandte Makromolekulare Chemie, 149(2413), p.87 - 99, 1987/00

 Times Cited Count:11 Percentile:54.1(Polymer Science)

no abstracts in English

Journal Articles

Durability of radiation-sterilized polymers,X ; Radiation resistance of high molecular weight polypropylene

; ;

Polym.Commun., 28, p.278 - 280, 1987/00

no abstracts in English

Journal Articles

Electric conduction of low density polyethylene induced by high dose rate gamma rays

*; ; *

Journal of Applied Physics, 54(8), p.4433 - 4438, 1983/00

 Times Cited Count:5 Percentile:34.45(Physics, Applied)

no abstracts in English

Journal Articles

Radiation-induced conductivity in polymeric insulating materials degraded under specified conditions

; Kuriyama, Isamu; *; *

IEEE Transactions on Electrical Insulation, 17(4), p.306 - 313, 1982/00

no abstracts in English

Journal Articles

Studies on radiation-induced current in polymeric insulating materials and their fine structure

; Kuriyama, Isamu; *; *

J.Mater.Sci., 17, p.3052 - 3056, 1982/00

 Times Cited Count:0 Percentile:0.01(Materials Science, Multidisciplinary)

no abstracts in English

JAEA Reports

Mechanical Properties of Radiation Polymerized Polyethylene

; Takehisa, Masaaki; Machi, Sueo

JAERI-M 5577, 19 Pages, 1974/03

JAERI-M-5577.pdf:0.7MB

no abstracts in English

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